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Amine Thermal Reclamation; Technology Development from Keywords: CO2 capture; amine; degradation; reclamation . amines during a reclaimer cycle. Amine reclaimer wastes (ARW) generated in CO2 capture processes demand suitable disposal means. Such wastes contain remaining amine, NH3 and other. Amine reclaimer wastes (ARW) generated in carbon capture and sequestration ( CCS) is categorized as a hazardous waste which needs proper disposal.

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Appendix D Thermal reclaiming of amine systems. This causes loss of valuable and expensive amine that has to be replaced together with reduced solvent performance. Some features of this site may not work without it.

Estimation of MEA loss is done trough the following equations:.

Appendix D Thermal reclaiming of amine systems

For case reclaiimer the MEA degradation would be significantly larger 1. The following reaction rate has been derived experimentally: This facility has been performing CO 2 capture from flue gas since [28;38].

The fourth objective was to perform a lab distillation of a contaminated amine solvent. According to this results, the reference value taken 0. An ordinary differential equation ODE solver was used to solve the set of differential equations. Metadata Show full item record.

Corrosion in Amine Reclaimer System

When the oxidative degradation is assumed to be 0. Amine reclaimer technologies Haaversen, Linn Christine Reclaime. Further, the external tube of heat exchangers experienced severe corrosion due to corrosive environment by higher accumulation of H2S and CO2 in the inlet of the exchanger. The degradation products also interact with MEA molecules according to reactions 3 and 4. The energy associated with this reclaiming is amiine, approximately 0.


This paper describes the root cause failure analysis of severe corrosion and erosion in amine reclaimer system including the overhead piping.

The reclaimer system was operated continuously, irrespective of the limit of oxozolidone content which is not as per the design specifications thereby increasing the exposure between carbon steel material parts of the system to the corrosive environment more than design.

The figure below show the results:. The following reactions show how the possible HSS are formed. The first objective in this thesis was to perform a literature study on the different amine reclaimer technologies with the intention to collect and summarize already published information. Output of the exchanger is sour water to the effluent treatment system.

Where, Estimation of heat stable salts formation follows from the removal rates and stoichimetry of the reactions: Abstract Carbon dioxide CO2 capture in post-combustion by the use of amines is one of several technologies known to reduce the release of CO2 to the atmosphere when burning fossil fuels. The second objective was to develop a model of a thermal reclaiming process for monoethanolamine MEA.


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Appendix D Thermal reclaiming of amine systems | Global CCS Institute

The table below shows the main performance characteristics of the capture plant and the lean solvent conditions for case 1B. Improvements of the model are suggested.

The column has shell and tube typed exchangers in the downstream-end of the reclaimer system. Oxidative degradation is the main form of MEA loss in a capture process. Concentration and temperature profiles were obtained. The model still needs some improvements.

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This reaction rate was used to estimated the MEA degradation rate revlaimer different O 2 concentrations in the Flue gas. Nevertheless, in many thermal reclaimers the concentration of amine is still high, transforming the thermal reclaimer more into a feed and bleed system [27].

This reaction model is a aine one, since in reality there are numerous degradation products detected in amine reclaimer samples that could form heat stable salts.